Publications
"Electrochemical Doping of Two-Dimensional Superatomic Materials," S. He, J. Yu, W. D. H. Stinson, C. A. Looney, S. Okuno, A. C. Crowther, D. V. Esposito, M. L. Steigerwald, X . Roy, C, Nuckolls, J. Am. Chem. Soc., 2024, 146, 28, 18861-18865.
"Electrostatically controlled spin polarization in Graphene-CrSBr magnetic proximity heterostructures," B. Yang, B. Bhujel, D. G. Chica, E. J. Telford, X. Roy, F. Ibrahim, M. Chshiev, M. Cosset-Chéneaul, B. J. van Wees, Nat. Comm., 2024, 15, 4459.
"Linker-Derived Contortion Controls Performance in Organic Polymer Pseudocapacitors," J. Gray, V. A. Posey, N. M. Orchanian, Z. Jin, M. L. Steigerwald, X. Roy, C. Nuckolls, Chem. Mater., 2024, 36, 9, 4861-4867.
"Impact of Spin-Entropy on the Thermoelectric Properties of a 2D Magnet," A. Canetta, S. Volosheniuk, S. Satheesh, J. P. A. Batista, A. Castellano, R. Conte, D. G. Chica, K. Watanabe, T. Taniguchi, X. Roy, H. S. J. van der Zant, M. Burghard, M. J. Verstraete, P. Gehring, Nano Lett., 2024, 24, 22, 6513-6520.
"Transient magnetoelastic coupling in CrSBr," Y. J. Bae, T. Handa, Y. Dai, M. E. Ziebel, A. D. Kent, J. Wang, H. Liu, A. Scheie, D. G. Chica, X. Xu, K. Shen, X. Roy, X.-Y. Zhu, Phys. Rev. B, 2024, 109, 104401.
"Photooxidation driven formation of Fe-Au linked ferrocene-based single-molecule junctions," W. Lee, L. Li, M. Camarasa-Gómez, D. Hernangómez-Pérez, X. Roy, F. Evers, M. S. Inkpen, L. Venkataraman, Nat. Comm., 2024, 15, 1439.
"CrSBr: An Air-Stable, Two-Dimensional Magnetic Semiconductor," M. E. Ziebel, M. L. Feuer, J. Cox, X.-Y. Zhu, C. R. Dean, X. Roy, Nano Letters, 2024, 24, 15, 4319–4329.
"Two-dimensional heavy fermions in the van der Waals metal CeSiI," V. A. Posey, S. Turkel, M. Rezaee, A. Devarakonda, A. K. Kundu, C. S. Ong, M. Thinel, D. G. Chica, R. A. Vitalone, R. Jing, S. Xu, D. R. Needell, E. Meirzadeh, M. L. Feuer, A. Jindal, X. Cui, T. Valla, P. Thunström, T. Yilmaz, E. Vescovo, D. Graf, X.-Y. Zhu, A. Scheie, A. F. May, O. Eriksson, D. N. Basov, C. R. Dean, A. Rubio, P. Kim, M. E. Ziebel, A. J. Millis, A. N. Pasupathy, X. Roy, Nature, 2024, 625, 483–488.
See related research briefing: "A layered metal confines heavy electrons to two dimensions," M. E. Ziebel, X. Roy, Nature, 2024.
See related research briefing: "A layered metal confines heavy electrons to two dimensions," M. E. Ziebel, X. Roy, Nature, 2024.
"Photocatalytic Activation of Aryl(trifluoromethyl) Diazos to Carbenes for High-Resolution Protein Labeling with Red Light," D. C. Cabanero, S.K. Kariofillism, A.C. Johns, J. Kim, J. Ni, S. Park, D. L. Parker Jr., C. P. Ramil, X. Roy, N. H. Shah, T. Rovis, J. Am. Chem. Soc. 2024, 146, 2, 1337-1345.
"Hyperbolic exciton polaritons in a van der Waals magnet," F.L. Ruta, S.Zhang, Y. Shao, S. L. Moore, S. Acharya, Z. Sun, S. Qiu, J. Geurs, B. S. Y. Kim, M. Fu, D. G. Chica, D. Pashov, X. Xu, D. Xiao, M. Delor, X.-Y. Zhu, A. J. Millis, X. Roy, J. C. Hone, C. R. Dean, M. I. Katsnelson, M. van Schilfgaarde, D. N. Basov. Nat. Comm. 2023, 14, 8261.
"Coexistence of Incoherent and Ultrafast Coherent Exciton Transport in a Two-Dimensional Superatomic Semiconductor," J. M. Baxter, C. S. Koay, D. Xu, S.-W. Cheng, J. A. Tulyagankhodjaev, P. Shih, X. Roy, M. Delor. J. Phys. Chem. Lett. 2023, 14, 45, 10249–10256.
"Electron and Spin Delocalization in [Co6Se8(PEt3)6] Superatoms," Y. Xu, J. Chen, A. P. Aydt, L. Zhang, I. Sergeyev, E. G. Keeler, B. Choi, S. He, D. R. Reichman, R. A. Friesner, C. Nuckolls, M. L. Steigerwald, X. Roy, A. McDermott. Chem. Phys. Chem. 2023, 25, 2, e202300064.
"Electron transport through supercrystals of atomically precise gold nanoclusters: a thermal bi-stability effect," T. Higaki, J. C. Russell, D. W. Paley, X. Roy, R. Jin, Chem. Sci. 2023, 14, 13191-13197.
"Designing Magnetic Properties in CrSBr through Hydrostatic Pressure and Ligand Substitution," E. J. Telford, D. G. Chica, M. E. Ziebel, K. Xie, N. S. Manganaro, C.-Y. Huang, J. Cox, A. H. Dismukes, X.-Y. Zhu, J. P. S. Walsh, T. Cao, C. R. Dean, X. Roy, Adv. Phys. Res. 2023, 2, 11, 2300036.
"Room-temperature wavelike exciton transport in a van der Waals superatomic semiconductor," J. A. Tulyagankhodjaev, P. Shih, J. Yu, J. C. Russell, D. G. Chica, M. E. Reynoso, H. Su, A. C. Stenor, X. Roy, T. C. Berkelbach, M. Delor, Science 2023, 382, 438-442.
"Interplay between local moment and itinerant magnetism in the layered metallic antiferromagnet TaFe1.14Te3," S. Y. Han, E. J. Telford, A. K. Kundu, S. J. Bintrim, S. Turkel, R. A. Wiscons, A. Zangiabadi, E.-S. Choi, T.-D. Li, M. L. Steigerwald, T. C. Berkelbach, A. N. Pasupathy, C. R. Dean, C. Nuckolls, X. Roy, Nano Lett. 2023, 23, 10449–10457.
"Exchange Bias between van der Waals Materials: Tilted Magnetic States and Field-free Spin-orbit-torque Switching," T. M. J. Cham , R. J. Dorrian, X. S. Zhang, A. H. Dismukes, D. G. Chica, A. F. May, X. Roy, D. A. Muller, D. C. Ralph , Y. Kelly Luo. Adv. Mater. 2023, 36, 13, 2305739.
"Functional Monolayers on a Superatomic Pegboard," S. He, S. Okuno, F. W. Ng, X. Pang, D. V. Esposito, N. M. Orchanian, M. L. Steigerwald, X. Roy, C. Nuckolls. J. Am. Chem. Soc. 2023, 145, 8314–8318.
"Anisotropically Fused Clusters Form a 2D Superatomic Sheet Exhibiting Polarized Light Emission," T. Handa, P. Shih, C. S. Koay, C. Nuckolls, X. Roy, T. C. Berkelbach, X.-Y. Zhu, J. Phys. Chem. C 2023, 127, 1519-1526.
"A few-layer covalent network of fullerenes," E. Meirzadeh, A. M. Evans, M. Rezaee, M. Milich, C. J. Dionne, T. P. Darlington, S. T. Bao, A. K. Bartholomew, T. Handa, D. J. Rizzo, R. A. Wiscons, M. Reza, A. Zangiabadi, N. Fardian-Melamed, A. C. Crowther, P. J. Schuck, D. N. Basov, X.-Y. Zhu, A. Giri, P. E. Hopkins, P. Kim, M. L. Steigerwald, J. Yang, C. Nuckolls, X. Roy, Nature 2023, 613, 71-76.
"Tunable interaction between excitons and hybridized magnons in a layered semiconductor," G. M. Diederich, J. Cenker, Y. Ren, J. Fonseca, D. G. Chica, Y. J. Bae, X.-Y. Zhu, X. Roy, T. Cao, D. Xiao, X. Xu, Nat. Nanotechnol. 2023, 18, 23-28.
"Highly Twisted Azobenzene Ligand Causes Crystals to Continuously Roll in Sunlight," A. K. Bartholomew, I. B. Stone , M. L. Steigerwald, T. H. Lambert, X. Roy, J. Am. Chem. Soc. 2022, 144, 16773–16777.
"Interfacial electric fields catalyze Ullmann coupling reactions on gold surfaces," I. Stone, R. Starr, N. Hoffmann, X. Wang, A. Evans, C. Nuckolls, T. Lambert, M. Steigerwald, T. Berkelbach, X. Roy, L. Venkataraman, Chem. Sci. 2022, 13, 10798-10805.
"Charge carrier coupling to the soft phonon mode in a ferroelectric semiconductor," M. E. Ziffer, L. Huber, F. Wang, V. A. Posey, J. C. Russell, T. Handa, X. Roy, X.-Y. Zhu, Phys. Rev. Mater. 2022, 6, 095401.
"Spin Waves and Magnetic Exchange Hamiltonian in CrSBr," A. Scheie, M. E. Ziebel, D. G. Chica, Y. J. Bae, X. Wang, A. I. Kolesnikov, X.-Y. Zhu, X. Roy, Adv. Sci. 2022, 9, 2202467.
"Anisotropic Gigahertz Antiferromagnetic Resonances of the Easy-Axis van der Waals Antiferromagnet CrSBr," T. M. J. Cham, S. Karimeddiny, A. H. Dismukes, X. Roy, D. C. Ralph, Y. K. Luo, Nano Lett. 2022, 22, 6716–6723.
"Spin injection by spin–charge coupling in proximity induced magnetic graphene," A. A. Kaverzin, T. S Ghiasi, A. H Dismukes, X. Roy, B. J. van Wees, 2D Mater. 2022, 9, 045003.
"Increased Molecular Conductance in Oligo[n]phenylene Wires by Thermally Enhanced Dihedral Planarization," W. Lee, S. Louie, A. M. Evans, N. M. Orchanian, I. B. Stone, B. Zhang, Y. Wei, X. Roy, C. Nuckolls, L. Venkataraman, Nano Lett. 2022, 22, 4919–4924.
"From atom-precise nanoclusters to superatom materials," C. M. Aikens, R. Jin, X. Roy, Tatsuya Tsukuda, J. Chem. Phys. 2022, 156, 170401.
"Exciton-Coupled Coherent Magnons in a 2D Semiconductor," Y. J. Bae, J. Wang, A. Scheie, J. Xu, D. G. Chica, G. M. Diederich, J. Cenker, M. E. Ziebel, Y. Bai, H. Ren, C. R. Dean, M. Delor, X. Xu, X. Roy, A. D. Kent, X.-Y. Zhu, Nature 2022, 609, 282–286.
"Coupling between magnetic order and charge transport in a two-dimensional magnetic semiconductor," E. J. Telford, A. H. Dismukes, R. L. Dudley, R. A. Wiscons, K. Lee, D. G. Chica, M. E. Ziebel, M. Han, A. Scheie, K. Watanabe, T. Taniguchi, J. Yu, S. Shabani, A. N. Pasupathy, C.Nuckolls, D. Xiao, Y. Zhu, X. Zhu, C. R. Dean, X. Roy, Nat. Mater. 2022, 21, 754-760.
"Visualizing Atomically-Layered Magnetism in CrSBr," D. J. Rizzo, A. S. McLeod, C. Carnahan, E. J. Telford, A. H. Dismukes, R. A. Wiscons, Y. Dong, C. Nuckolls, C. R. Dean, A. N. Pasupathy, X. Roy, D. Xiao, D. N. Basov, Adv. Mater. 2022, 34, 2201000.
"The Magnetic Genome of Two-Dimensional van der Waals Materials," Q. H. Wang, A. Bedoya-Pinto, M. Blei, A. H. Dismukes, A. Hamo, S. Jenkins, M. Koperski, Y. Liu, Q. Sun, E. J. Telford, H. H. Kim, M. Augustin, U. Vool, J. Yin, L. H. Li, A. Falin, C. R. Dean, F. Casanova, R. F. L. Evans, M. Chshiev, A. Mishchenko, C. Petrovic, R. He, L. Zhao, A. W. Tsen, B. D. Gerardot, M. Brotons-Gisbert, Z. Guguchia, X. Roy, S. Tongay, Z. Wang, M. Z. Hasan, J. Wrachtrup, A. Yacoby, A. Fert, S. Parkin, K. S. Novoselov, P. Dai, L. Balicas, and E. J. G. Santos, ACS Nano. 2022, 16, 6960−7079.
"Broad-band Chiral Absorbance of Visible Light," S. Y. Han, R. K. Mow, A. K. Bartholomew, F. Ng, M. L. Steigerwald, X. Roy, C. Nuckolls, and R.A. Wiscons. J. Am. Chem, Soc. 2022, 144, 5263–5267.
"High-Spin Superatom Stabilized by Dual Subshell Filling," D. Bista, A. P. Aydt, K. J. Anderton, D. W. Paley, T. A. Betley, A. C. Reber, V. Chauhan, A. K. Bartholomew, X. Roy, and S. N. Khanna, J. Am. Chem. Soc. 2022, 144, 5172–5179.
"Reversible strain-induced magnetic phase transition in a van der Waals magnet," J. Cenker, S. Sivakumar, K. Xie, A. Miller, P. Thijssen, Z. Liu, A. H. Dismukes, J. Fonseca, E. Anderson, X.-Y. Zhu, X. Roy, D. Xiao, J.-H. Chu, T. Cao, X. Xu, Nature Nanotechnol. 2022, 17, 256–261.
"Superatom Regiochemistry Dictates the Assembly and Surface Reactivity of a Two-Dimensional Material," A. K. Bartholomew, E. Meirzadeh, I. B. Stone, C. S. Koay, C. Nuckolls, M. L. Steigerwald, A. C. Crowther, X. Roy, J. Am. Chem. Soc. 2022, 144, 1119–1124.
"Site-Selective Surface Modification of 2D Superatomic Re6Se8," S. He, A. M. Evans, E. Meirzadeh, S. Y. Han, J. C. Russell, R. A. Wiscons, A. K. Bartholomew, D. A. Reed, A. Zangiabadi, M. L. Steigerwald, C. Nuckolls, X. Roy, J. Am. Chem. Soc. 2022, 144, 74–79.
"Controlling Ligand Coordination Spheres and Cluster Fusion in Superatoms," D. A. Reed, T. J. Hochuli, N. A. Gadjieva, S. He, R. A. Wiscons, A. M. Champsaur, M. L. Steigerwald, X. Roy, C. Nuckolls, J. Am. Chem. Soc. 2022, 144, 306–313
"Exchange Bias from Frustrated Spins," E. Meirzadeh, S. Y. Han, X. Roy, ACS Cent. Sci. 2021, 7, 1295-1297.
"A single-molecule blueprint for synthesis," I. B. Stone, R. L. Starr, Y. Zang, C. Nuckolls, M. L. Steigerwald, T. H. Lambert, X. Roy, L. Venkataraman, Nature Rev. Chem. 2021, 5, 695–710.
"Interlayer electronic coupling on demand in a 2D magnetic semiconductor," N. P. Wilson, K. Lee, J. Cenker, K. Xie, A. H. Dismukes, E. J. Telford, J. Fonseca, S. Sivakumar, C. Dean, T. Cao, X. Roy, X. Xu, X.-Y. Zhu, Nature Mater. 2021, 20, 1657–1662.
"Superatomic solid solutions," J. Yang, J. C. Russell, S. Tao, M. Lessio, F. Wang, A. C. Hartnett, S. R. Peurifoy, E. A. Doud, E. S. O’Brien, N. Gadjieva, D. R. Reichman, X.-Y Zhu, A. C. Crowther, S. J. L. Billinge, X. Roy, M. L. Steigerwald, C. Nuckolls, Nature Chem. 2021, 13, 607-613.
"High Performance Organic Pseudocapacitors via Molecular Contortion," J. C. Russell, V. A. Posey, J. Gray, R. May, D. A. Reed, L. Marbella, M. L. Steigerwald, Y. Yang, X. Roy, C. Nuckolls, S. R. Peurifoy, Nature Mater. 2021, 20, 1136-1141.
"Electrical and Thermal Generation of Spin Currents by Magnetic Bilayer Graphene," T. S. Ghiasi, A. A. Kaverzin, A. H. Dismukes, D. K. de Wal, X. Roy, B. J. van Wees, Nature Nanotechnol. 2021, 16, 988-794.
"Polytypism, Anisotropic Transport, and Weyl Nodes in the van der Waals Metal TaFeTe4," R. A. Wiscons, Y. Cho, S. Y. Han, A. H. Dismukes, E. Meirzadeh, C. Nuckolls, T. C. Berkelbach, X. Roy, J. Am. Chem. Soc. 2021, 143, 109-113.
"Magnetic order and symmetry in the 2D semiconductor CrSBr," K. Lee, A. H. Dismukes, E. J. Telford, R. A. Wiscons, X. Xu, C. Nuckolls, C. R. Dean, X. Roy, X.-Y. Zhu, Nano Lett. 2021, 21, 3511-3517.
"Intermolecular Resonance Correlates Electron Pairs Down a Supermolecular Chain: Antiferromagnetism in K-Doped p-Terphenyl," N. A. Gadjieva, P. Szirmai, O. Sági, P. Alemany, A. K. Bartholomew, I. Stone, S. Conejeros, D. W. Paley, R. Hernández Sánchez, B. Fowler, S. R. Peurifoy, B. Náfrádi, L. Forró, X. Roy, P. Batail, E. Canadell, M. L. Steigerwald, C. Nuckolls, J. Am. Chem. Soc. 2020, 142, 20624-20630.
"Cyclopropenylidenes as Strong Carbene Anchoring Groups on Au Surfaces," E. A. Doud*, R. L. Starr*, G. Kladnik*, A. Voevodin*, E. Montes, N. P. Arasu, Y. Zang, P. Zahl, A. Morgante, L. Venkataraman, H. Vazquez, D. Cvetko, X. Roy, J. Am. Chem. Soc. 2020, 142, 19902-19906.
"Single-Electron Currents in Designer Single-Cluster Devices," S. Gunasekaran*, D. A. Reed*, D. W. Paley, A. K. Bartholomew, L. Venkataraman, M. L. Steigerwald, X. Roy, C. Nuckolls, J. Am. Chem. Soc. 2020, 142, 14924–14932.
"Mechanically-tunable Quantum Interference in Ferrocene-based Single-Molecule Junctions," M. Camarasa-Gomez, D. Hernangomez-Perez, M. S. Inkpen, G. Lovat, E-D. Fung, X. Roy, L. Venkataraman, F. Evers, Nano Lett. 2020, 20, 6381–6386.
"Shape Matching in Superatom Chemistry and Assembly," J. Yang, F. Wang, J. C. Russel, T. J. Hochuli, X. Roy, M. L. Steigerwald, X.-Y. Zhu, D. W. Paley, C. Nuckolls, J. Am. Chem. Soc. 2020, 142, 11993-11998.
"FeOF/TiO2 Hetero-Nanostructures for High Areal-Capacity Fluoride Cathodes," W. Li, Y. Chen, A. Zangiabadi, X. Xiao, W. Huang, Q. Cheng, S. Lou, S. Lou, H. Zhang, A. Cao, X. Roy, Y. Yang, ACS Appl. Mater. Interfaces 2020, 12, 33803-33809.
"Layered Antiferromagnetism Induces Large Negative Magnetoresistance in the van der Waals Semiconductor CrSBr," E. J. Telford*, A. H. Dismukes*, K. Lee, M. Cheng, A. Wieteska, Y.-S. Chen, X. Xu, A. N. Pasupathy, X.-Y. Zhu, C. R. Dean, X. Roy, Adv. Mater. 2020, 32, 2003240. (arXiv:2005.06110)
"Charge Carrier Scattering and Ultrafast Auger Dynamics in Two-Dimensional Superatomic Semiconductors," H. Kim, K. Lee, A. H. Dismukes, B. Choi, X. Roy, X.-Y. Zhu, M. Bonn, Appl. Phys. Lett. 2020, 116, 201109.
"Strong Polaronic Effect in a Superatomic Two-Dimensional Semiconductor," Q. Li, F. Liu, J. C. Russell, X. Roy, X.-Y. Zhu, J. Chem Phys. 2020, 152, 171101.
"Gold-Carbon Contact from Oxidative Addition of Aryl Iodides," R. L. Starr, T. Fu, E. A. Doud, I. Stone, X. Roy, L. Venkataraman, J. Am. Chem. Soc. 2020, 142, 7128-7133.
"Dimensional Control of Assembling Metal Chalcogenide Clusters," N. A. Gadjieva, A. M. Champsaur, M. L. Steigerwald, X. Roy, C. Nuckolls, Eur. J. Inorg. Chem. 2020, 1245-1254.
"Superatoms in Materials Science," E. A. Doud*, A. Voevodin*, T. J. Hochuli, A. M. Champsaur, C. Nuckolls, X. Roy, Nature Rev. Mater. 2020, 5, 371–387.
"Doping-Induced Superconductivity in the van der Waals Superatomic Crystal Re6Se8Cl2," E. J. Telford*, J. C. Russell*, J. R. Swann, B. Fowler, X. Wang, K. Lee, A. Zangiabadi, K. Watanabe, T. Tanigushi, C. Nuckolls, P. Batail, X.-Y. Zhu, J. A. Malen, C. R. Dean, X. Roy, Nano Lett. 2020, 20, 1718-1724.
"Ligand Effects on the Electronic Structure of Cobalt Sulfide Clusters: A Combine Experimental and Theoretical Study," G. Liu, V. Chauhan, A. P. Aydt, S. M. Ciborowski, A. Pinkard, Z. Zhu, X. Roy, S. N. Khanna, K. H. Bowen, J. Phys. Chem. C 2019, 123, 25121-25127.
"Hierarchical Coherent Phonons in a Superatomic Semiconductor," K. Lee, S. F. Maehrlein, X. Zhong, D. Meggiolaro, J. C. Russell, D. A. Reed, B. Choi, F. De Angelis, X. Roy, X.-Y. Zhu, Adv. Mater. 2019, 31, 1903209.
"In Situ Coupling of Single Molecules Driven by Gold-Catalyzed Electrooxidation," Y. Zang*, I. Stone*, M. S. Inkpen, F. Ng, T. H. Lambert, C. Nuckolls, M. L. Steigerwald, X. Roy, L. Venkataraman, Angew. Chem. Int. Ed. 2019, 58, 16008-16012.
"Solution-Processble Superatomic Thin-Films," J. Yang, B. Zhang, A. D. Christodoulides, A. Zangiabadi, S. R. Peurifoy, C. K. McGinn, L. Dai, E. Meirzadeh, X. Roy, M. L. Steigerwald, I. Kymissis, J. A. Malen, C. Nuckolls, J. Am. Chem. Soc. 2019, 141, 10967-10971.
"Nickel Phosphinidene Molecular Clusters from Organocyclophosphine Precursors," E. A. Doud, C. J. Butler, D. W. Paley, X. Roy, Chem. Eur. J. 2019, 25, 10840-10844.
"Mo6S3Br6: An Anisotropic 2D Superatomic Semiconductor," X. Zhong, K. Lee, D. Meggiolaro, A. H. Dismukes, B. Choi, F. Wang, C. Nuckolls, D. W. Paley, P. Batail, F. De Angelis, X. Roy, X.-Y. Zhu, Adv. Funct. Mater. 2019, 29, 1902951.
"Microporous Battery Electrodes from Molecular Cluster Precursors," A. P. Aydt*, B. Qie*, A. Pinkard*, L. Yang, Q. Cheng, S. J. L. Billinge, Y. Yang, X. Roy, ACS Appl. Mater. Interfaces 2019, 11, 11292-11297.
"Tuning the electronic properties of hexanuclear cobalt sulfide superatoms via ligand substitution," G. X. Liu, A. Pinkard, S. M. Ciborowski, V. Chauhan, Z. G. Zhu, A. P. Aydt, S. N. Khanna, X. Roy, K. H. Bowen, Chem. Sci. 2019, 10, 1760-1766.
"Determination of the Structure and Geometry of N-Heterocyclic Carbenes on Au(111) using High-Resolution Spectroscopy," G. Lovat, E. A. Doud, D. Lu, G. Kladnik, M. S. Inkpen, M. L. Steigerwald, D. Cvetko, M. S. Hybertsen, A. Morgante, X. Roy, L. Venkataraman, Chem. Sci. 2019, 10, 930-935.
"Spontaneous Electronic and Formation and Switchable Behaviors in a Phase-Rich Superatomic Crystal," E. S. O’Brien, J. C. Russell, M. Bartnof, A. D. Christodoulides, K. Lee, J. A. DeGayner, D. W. Paley, A. J. H. McGaughey, W.-L. Ong, J. A. Malen, X.-Y. Zhu, X. Roy, J. Am. Chem. Soc. 2018, 140, 15601-15605.
"Designing Three-Dimensional Architectures for High-Performance Electron Accepting Pseudocapacitors," S. R. Peurifoy*, J. C. Russell*, T. J. Sisto, Y. Yang, X. Roy, C. Nuckolls, J. Am. Chem. Soc. 2018, 140, 10960-10964.
"Modulating the Hierarchical Fibrous Assembly of Au Nanoparticles with Atomic Precision," Q. Li, J. C. Russell, T.-Y. Luo, X. Roy, N. L. Rossi, R. Jin, Nature Commun. 2018, 9, 3871.
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"Two-Dimensional Hierarchical Semiconductor with Addressable Surfaces," B. Choi, K. Lee, A. Voevodin, J. Wang, M. L. Steigerwald, P. Batail, X.-Y. Zhu, X. Roy, J. Am. Chem. Soc. 2018, 140, 9369-9373.
"In Situ Formation of N-Heterocyclic Carbene-Bound Single-Molecule Junctions," E. A. Doud*, M. S. Inkpen*, G. Lovat, E. Montes, D. W. Paley, M. L. Steigerwald, H. Vazquez, L. Venkataraman, X. Roy, J. Am. Chem. Soc. 2018, 140, 8944-8949.
"Electron Cartography in Clusters," R. H. Sánchez, A. M. Champsaur, B. Choi, S. G. Wang, W. Bu, X. Roy, Y.-S. Chen, M. L. Steigerwald, C. Nuckolls, D. W. Paley, Angew. Chem. Int. Ed. 2018, 57, 13815-13820.
"Two-Dimensional Fullerene Assembly from an Exfoliated van der Waals Template," K. Lee, B. Choi, I. Jen-La Plante, M. V. Paley, X. Zhong, A. C. Crowther, J. S. Owen, X.-Y. Zhu, X. Roy, Angew. Chem. Int. Ed. 2018, 57, 6125-6129.
"Multifunctional Vesicles from a Self-Assembled Cluster-Containing Block Copolymer," A. Voevodin, L. M. Campos, X. Roy, J. Am. Chem. Soc. 2018, 140, 5607-5611.
"Molecular Clusters: Nanoscale Building Blocks for Solid-State Chemistry," A. Pinkard, A. Champsaur, X. Roy, Acc. Chem. Res. 2018, 51, 919-929.
"Superatomic Two-Dimensional Semiconductor," X. Zhong, K. Lee, B. Choi, D. Meggiolaro, F. Liu, C. Nuckolls, A. N. Pasupathy, F. De Angelis, P. Batail, X. Roy, and X.-Y. Zhu, Nano Lett. 2018, 18, 1483-1488.
"Controlled Electrochemical Intercalation of graphene/h-BN van der Waals Heterostructures," S. Y. Zhao, G. A. Elbaz, D. K. Bediako, C. Yu, D. K. Efetov, Y. Guo, J. Ravichandran, K.-A. Min, S. Hong, T. Taniguchi, K. Watanabe, L. E. Brus, X. Roy, P. Kim, Nano Lett. 2018, 18, 460-466.
"Electronically Transparent Au–N Bonds for Molecular Junctions," Y. Zang*, A. Pinkard*, Z.-F. Liu, J. B. Neaton, M. L. Steigerwald, X. Roy, and L. Venkataraman, J. Am. Chem. Soc. 2017, 139, 14845-14848.
"Room-temperature current blockade in atomically defined single-cluster junctions," G. Lovat*, B. Choi*, D. W. Paley, M. L. Steigerwald, L. Venkataraman, X. Roy, Nature Nanotechnol. 2017, 12, 1050-1054
"Single-crystal-to-single-crystal intercalation of a low-bandgap superatomic crystal," E. S. O’Brien, M. T. Trinh, R. L. Kann, J. Chen, G. A. Elbaz, A. Masurkar, T. L. Atallah, M. V. Paley, N. Patel, D. W. Paley, I. Kymissis, A. C. Crowther, A. J. Millis, D. R. Reichman, X.Y. Zhu, X. Roy, Nature Chem. 2017, 9, 1170-1174.
"Phonon Speed, Not Scattering, Differentiates Thermal Transport in Lead Halide Perovskites," G. A. Elbaz, W.-L. Ong, E. A. Doud, P. Kim, D. W. Paley, X. Roy, J. A. Malen, Nano Lett. 2017, 17, 5734-5739.
"Dimerization of endohedral fullerene in a superatomic crystal," A. Voevodin, L. Abella, E. Castro, D. W. Paley, L. M. Campos, A. Rodriguez-Fortea, J. M. Poblet, L. Echegoyen, X. Roy, Chem. Eur. J. 2017, 23, 13305-13308.
"Two-Dimensional Nanosheets from Redox-Active Superatoms," A. M. Champsaur, J. Yu, X. Roy, D. W. Paley, M. L. Steigerwald, C. Nuckolls, C. M. Bejger, ACS Cent. Sci. 2017, 3, 1050-1055.
"Unbalanced Hole and Electron Diffusion in Lead Bromide Perovskites," G. A. Elbaz, D. B. Straus, O. E. Semonin, T. D. Hull, D. W. Paley, P. Kim, J. S. Owen, C. R. Kagan, X. Roy. Nano Lett. 2017, 17, 1727-1732.
"Orientational order controls crystalline and amorphous thermal transport in superatomic crystals," W.-L. Ong, E. S. O’Brien, P. S. M. Dougherty, D. W. Paley, C. F. Higgs III, A. J. H. McGaughey, J. A. Malen, X. Roy, Nature Mater. 2017, 16, 83-88.
"Distinct Properties of the Triplet Pair State from Singlet Fission," M. T. Trinh, A. Pinkard, A. B. Pun, S. N. Sanders, E. Kuramasary, M. Y. Sfeir, L. M. Campos, X. Roy, X.-Y. Zhu, Science Adv. 2017, 3, e1700241.
"High Oxidation State Iridium Mono-mu-oxo Dimers Related to Water Oxidation Catalysis," L. S. Sharninghausen, S. B. Sinha, D. Y. Shopov, B. Choi, B. Q. Mercado, X. Roy, D. Balcells, G. W. Brudvig, R. H. Crabtree, J. Am. Chem. Soc. 2016, 138, 15917-15926.
"Limits of Carrier Diffusion in n-Type and p-Type CH3NH3PbI3 Perovskite Single Crystals," O. E. Semonin, G. E. Elbaz, D. Strauss, T. D. Hull, D. W. Paley, A. M. Van der Zande, I. Kymissis, C. Kagan, X. Roy, J. S. Owen, J. Chem. Phys. Lett. 2016, 7, 3510-3518.
"Building Diatomic and Triatomic Superatom Molecules," A. M. Champsaur, A. Velian, D. W. Paley, B. Choi, X. Roy, M. L. Steigerwald, C. Nuckolls, Nano Lett. 2016, 16, 5273-5277.
"Patterning Superatom Dopants on Transition Metal Dichalcogenides," J. Yu, C.-H. Lee, D. Bouilly, M. Han, P. Kim, M. L. Steigerwald, X. Roy, C. Nuckolls, Nano Lett. 2016, 16, 3385-3389.
"van der Waals Solids from Self-Assembled Nanoscale Building Blocks," B. Choi, J. Yu, D. W. Paley, M. T. Trinh, M. V. Paley, J. M. Karch, A. C. Crowther, C.-H. Lee, R. A. Lalancette, X.-Y. Zhu, P. Kim, M. L. Steigerwald, C. Nuckolls, X. Roy, Nano Lett. 2016, 16, 1445-1449.
“Solvent-Dependent Conductance Decay Constants in Single Cluster Junctions,” B. Choi, S. Ahn, B. Capozzi, M. L. Steigerwald, C. Nuckolls, L. Venkataraman, X. Roy, Chem. Sci. 2016, 7, 2701-2705.
"Ligand Control of Manganese Telluride Molecular Cluster Core Nuclearity," B. Choi, D. W. Paley, T. Siegrist, M. L. Steigerwald, X. Roy, Inorg. Chem. 2015, 54, 8348-8355.
"Quantitative Intramolecular Singlet Fission in Bipentacenes," S. N. Sanders, E. Kumarasamy, A. B. Pun, M. T. Trinh, B. Choi, J. Xia, E. J. Taffet, J. Z. Low, J. R. Miller, X. Roy, X.-Y. Zhu, M. L. Steigerwald, M. Y. Sfeir, L. M. Campos, J. Am. Chem. Soc. 2015, 137, 8965-8972.
"Assembling Hierarchical Cluster Solids with Atomic Precision," A. Turkiewicz, D. W. Paley, T. Besara, G. Elbaz, A. Pinkard, T. Siegrist, X. Roy, J. Am. Chem. Soc. 2014, 136, 15873-15876.
"Ferromagnetic Ordering in Superatomic Solids," C.-H. Lee, L. Liu, A. Turkiewicz, C. Bejger, T. Goko, C. Arguello, B. Frandsen, S. Cheung, T. Medina, T. J. S. Munsie, R. d’Ortenzio, G. M. Luke, Tiglet Besara, R. A. Lalancette, T. Siegrist, P. W. Stephens, A. C. Crowther, L. E. Brus, Y. Matsuo, E. Nakamura, Y. J. Uemura, P. Kim, C. Nuckolls, M. L. Steigerwald, X. Roy, J. Am. Chem. Soc., 2014, 136, 16926-16931.
"Nanoscale Atoms in Solid-State Chemistry," X. Roy, C.-H. Lee, A. C. Crowther, C. L. Schenck, T. Besara, R. A. Lalancette, T. Siegrist, P. W. Stephens, L. E. Brus, P. Kim, M. L. Steigerwald, C. Nuckolls, Science, 2013, 341, 157-160.
"Quantum Soldering of Individual Quantum Dots," X. Roy, C. L. Schenck, S. Ahn, R. A. Lalancette, L. Venkataraman, C. Nuckolls, M. L. Steigerwald, Angew. Chem. Int. Ed. 2012, 51, 12473-12476.
"Electronic Transport and Mechanical Stability of Carboxyl Linked Single-Molecule Junctions," S. Ahn, S. V. Aradhya, R. S. Klausen, B. Capozzi, X. Roy, M. L. Steigerwald, C. Nuckolls, L. Venkataraman, PCCP 2012, 14, 13841-13845.
"Molecular Scaffolding of Prussian Blue Analogues Using a Phenanthroline-Extended Triptycene Ligand," X. Roy, J. H. Chong, B. O. Patrick, M. J. MacLachlan, Cryst. Growth Des. 2011, 11, 4551-4558.
"Prussian Blue Nanocontainers: Selectively Permeable Hollow Metal-Organic Capsules from Block Ionomer Emulsion-Induced Assembly," X. Roy, J. K.-H. Hui, M. Rabnawaz, G. Liu, M. J. MacLachlan, J. Am. Chem. Soc. 2011, 133, 8420-8423.
"Soluble Prussian Blue Nanoworms from the Assembly of Metal–Organic Block Ionomers," X. Roy, J. K.-H. Hui, M. Rabnawaz, G. Liu, M. J. MacLachlan, Angew. Chem. Int. Ed. 2011, 50, 1597-1602.
"Liquid Crystal Templating in Ammonia: A Novel and Facile Route to Micro- and Mesoporous Metal Nitride/Carbon Composites," H. Qi, X. Roy, K. E. Shopsowitz, J. K.-H. Hui, M. J. MacLachlan, Angew. Chem. Int. Ed. 2010, 122, 9934-9937.
"Coordination Chemistry: New Routes to Mesostructured Materials," X. Roy, M. J. MacLachlan, Chem. Eur. J. 2009, 15, 6552-6559.
"Mesostructured Prussian Blue Analogues," X. Roy, L. K. Thompson, N. Coombs, M. J. MacLachlan, Angew. Chem. Int. Ed. 2008, 47, 511-514.
"Ultraporous Nanosheath Materials by Layer-by-Layer Deposition onto Co-Continuous Polymer Blend Templates," X. Roy, P. Sarazin, B. D Favis, Adv. Mater. 2006, 18, 1015-1019.
"Controlled Preparation and Properties of Porous Poly(L-lactide) Obtained from a Co-Continuous Blend of Two Biodegradable Polymers," P. Sarazin, X. Roy, B. D. Favis, Biomaterials 2004, 25, 5965-5978.
"Study of Tire Particle Mixing in a Moving and Stirred Bed Vacuum Pyrolysis Reactor," J. Yang, M. Gupta, X. Roy, C. Roy, Can. J. Chem. Eng. 2004, 82, 510-519.